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class="title">三氯化鐵在蝕刻和選礦廢水中的應用</h1> <div class="info_title clearfix"> <h3 class="title_bar"> 發布日期：<span>2015-10-13 00:00</span> 來源：<span>http://www.buildinstantrapport.com</span> 點擊：<span><script src="http://www.buildinstantrapport.com/data/include/newshits.php?id=248"></script></span> </h3> <div class="share">  <div id="bdshare" class="bdshare_t bds_tools get-codes-bdshare"> <a class="bds_tsina"></a> <a class="bds_qzone"></a> <a class="bds_tqq"></a> <a class="bds_hi"></a> <a class="bds_qq"></a> <a class="bds_tieba"></a> <span class="bds_more">更多</span> <a class="shareCount"></a> </div> <script type="text/javascript" id="bdshare_js" data="type=tools&uid=6513684" ></script> <script type="text/javascript" id="bdshell_js"></script> <script type="text/javascript"> document.getElementById("bdshell_js").src = "http://bdimg.share.baidu.com/static/js/shell_v2.js?cdnversion=" + Math.ceil(new Date()/3600000) </script>  </div> </div> <div class="content"><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　<a href='http://www.buildinstantrapport.com/product/slht/' target='_blank' class='key_tag'><font color=#136ec2><strong>三氯化鐵</strong></font></a>作為<span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 48px;"><a href='http://www.buildinstantrapport.com/' target='_blank' class='key_tag'><font color=#136ec2><strong>凈水絮凝劑</strong></font></a></span>的一種，在水處理方面有著重要的效果，工業級三氯化鐵GB/T1621-2008 用于<a href='http://www.buildinstantrapport.com/product/wushuichuli88/' target='_blank' class='key_tag'><font color=#136ec2><strong>污水處理</strong></font></a>，以除掉水中的重金屬和磷酸鹽。在通常的用水、工業用水、工業廢水、城市污水的處理上，液體三氯化鐵是高效的水處理凈水絮凝劑，能有限改善水質，沉積重金屬及硫化物、脫色、脫臭、除油、滅菌、除磷，與其他水處理絮凝劑比較，效果十分顯著。</span></p><p style="text-align:center"><img src="/data/upload/image/20151013/1444708803358532.jpg" title="三氯化鐵.jpg" alt="三氯化鐵.jpg" width="320" height="220" border="0" vspace="0" style="width: 320px; height: 220px;"/></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';"></span><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">　　在平常見到的固體三氯化鐵吸水性很強，水解出來的三價鐵離子具有強壯的氧化性，能置換二價的銅，鐵，不銹鋼，因此它廣泛用于五金職業，起蝕刻效果，這一技能的運用，大大提高了五金加工職業的溝通加工功率，讓許多沖壓不也許完結的精度，速度，成為了也許。恰是這些優異的特質，使得三氯化鐵的使用愈加廣泛。在自來水處理中，</span><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">凈水絮凝劑</span><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">是無機混凝劑的發展方向。用</span><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">凈水絮凝劑</span><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">替代鋁混凝劑是準確的挑選。這些年，歐美國家制定的飲用水規范中對鋁的含量作了嚴厲約束。并且已遍及改用鐵混凝劑，而鋁混凝劑逐漸被篩選。</span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　一般在水中磷主要以磷酸及其酸根形式存在，而三氯化鐵中三價鐵離子在酸性環境中可與磷酸（包括其酸根）形成極難容的磷酸鐵沉淀，從而達到除磷的作用.三氯化鐵是無機絮凝劑，具體投加量需要小試才行，因為不同水質需要對應不同比例的絮凝劑，我們可以根據污水的性質進行混凝實驗來確定混凝劑的投加量，一般聚鋁、三氯化鐵的投加量在50~300mg/L，一般<a href='http://www.buildinstantrapport.com/product/jbxa/' target='_blank' class='key_tag'><font color=#136ec2><strong>聚丙烯酰胺</strong></font></a>的投加量為10~20mg/L，主要是做助凝劑用，使鋁鹽、鐵鹽的絮體連接為更大的易分離的絮體。<br/></span></p><p style="line-height: 3em;"><strong><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　一、三氯化鐵蝕刻不銹鋼銅鋁可作為氯化劑</span></strong><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';"><br/></span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　隨著電子技術的發展，越來越需要許多幾何形狀復雜、精密度要求高而機械加工難以實現的超薄形工件。而照相腐蝕（或稱金屬蝕刻）方法卻易達到部件平整、無毛刺、圖形復雜的要求，且加工周期短、成本低。它的化學原理是利用三氯化鐵水溶液作為腐蝕劑與金屬反應：</span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';"> 2FeCl 3 ＋ F e＝ 2FeCl 2 2FeCl 3 ＋ C u＝ CuCl 2 ＋ 2FeCl 2<br/></span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　在氯離子和氧化劑共存的條件下就可以發生金屬腐蝕。 FeCl 3 作為一種較強的氧化劑，其腐蝕作用取決于 Fe 3 + ＋ e → Fe 2+ 反應的氧化還原電位（ 0.77V ），加之溶液中含有大量的氯離子，且 PH 值低、酸性強，所以對金屬有強烈的腐蝕傾向。由腐蝕反映原理可知，三氯化鐵隨著反應進行， Fe 3+ 離子濃度越來越低，而 Fe 2+ 離子濃度越來越高。一般經驗數據表明：在 Be 4 2 0 的<a href='http://www.buildinstantrapport.com/product/144.html' target='_blank' class='key_tag'><font color=#136ec2><strong>三氯化鐵溶液</strong></font></a>中的 Fe 2+ 離子濃度超過一定量時，腐蝕劑對金屬腐蝕速度就顯著下降，腐蝕質量變差，此時就需要更新。若經常更換腐蝕溶液，一則對環境產生污染，二則造成浪費，提高產品成本，如果能把 Fe 2+ 氧化再生就可能解決這些問題。<br/></span></p><p style="line-height: 3em;"><strong><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　二、三氯化鐵在選礦廢水中的應用</span></strong><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';"><br/></span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　三氯化鐵運用于選礦其實和用于蝕刻行業原理差不多，都是通過三氯化鐵的強氧化性，可以把礦物巖石里的鐵，銅，鋁等成分溶解出來，然后通過離子分析的原理再一步一步電離出來沉淀出來，得到相應的金屬固體。選礦工程的研究內容是將低品位的礦物進行加工、提純，主要目的是提高礦物的品位，去除礦物的雜質，例如去除煤炭中的灰分、硫、磷等雜質，選礦工程的對象主要有金屬礦石、煤炭等，選礦的手段主要是物理方法和化學方法：根據礦石的礦物性質，主要是不同礦物的物理、化學或物理化學性質，采用不同的方法，將有用礦物與脈石礦物分開，并使各種共生的有用礦物盡可能相互分離，除去或降低有害雜質，以獲得冶煉或其他工業所需原料的分選過程。<br/></span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　根據礦石中不同礦物的物理、化學性質，把礦石破碎磨細以后，采用重選法、浮選法、磁選法、電選法等，將有用礦物與脈石礦物分開，并使各種共生的有用礦物盡可能相互分離，除去或降低有害雜質，以獲得冶煉或其他工業所需原料的過程。選礦使有用組分富集，減少冶煉或其他加工過程中的燃料、運輸等的消耗，使低品位的貧礦石能得到經濟利用。選礦試驗所得數據，是礦床評價及建廠設計的主要依據。從脈石中有時從其他礦物中分選出金屬礦物或有價值的別種礦物的機械加工方法。<br/></span></p><p style="line-height: 3em;"><span style="font-size: 14px; font-family: 微軟雅黑, 'Microsoft YaHei';">　　三氯化鐵主要是化學法：利用礦物化學性質的不同，采用化學方法或化學與物理相結合的方法分離和回收有用成分，得到化學精礦。這種方法比通常的物理選礦法適應性強，分離效果好，但成本較高，常用于處理用物理選礦方法難于處理或無法處理的礦物原料、中間產品或尾礦。隨著成分復雜的、難選的和細粒的礦物原料日益增多，物理和化學選礦聯合流程的應用越來越受到重視?；瘜W選成功應用的實例有氰化法提金、酸浸-沉淀-浮選、離析-浮選處理氧化銅礦-<A a 離子交換和<A a 細菌浸取等技術的應用，進一步促進了化學選的發展。它的發展趨向是：研制更有效的浸取劑和萃取劑，發展生物化學方法，降低能耗和成本，防止環境污染。此外，還有礦物原料在斜面運動或碰撞時利用其摩擦系數、碰撞恢復系數的差異進行選別的<A a 摩擦與彈跳選等。</span></p></div> <h3 class="tag">相關標簽：<a href="http://www.buildinstantrapport.com/tag/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%81">三氯化鐵</a> </h3> <div class="page">上一篇：<a href="http://www.buildinstantrapport.com/news/246.html">某云母制品污水站改造方案</a><br />下一篇：<span><a href="http://www.buildinstantrapport.com/news/249.html">三氯化鐵的污水處理作用效果</a></span></div> </div>  <div class="relate_list" style="display:none"> <div class="relateproduct relate"><h4>相關產品：</h4> <div class="content"> <ul id="relate_p" class="product_list clearfix"> <li> <a href="http://www.buildinstantrapport.com/product/138.html" title="六水三氯化鐵" class="img"> <img src="http://www.buildinstantrapport.com/data/images/product/thumb_20150910160355_168.jpg" alt="六水三氯化鐵" width="120" height="96" /> </a> <h3><a href="http://www.buildinstantrapport.com/product/138.html" title="六水三氯化鐵">六水三氯化鐵</a></h3> </li> <li> <a 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