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class="title">硫酸亞鐵處理廢水的混凝過程及與其它絮凝劑的投加順序</h1> <div class="info_title clearfix"> <h3 class="title_bar"> 發布日期：<span>2015-12-08 00:00</span> 來源：<span>http://www.buildinstantrapport.com</span> 點擊：<span><script src="http://www.buildinstantrapport.com/data/include/newshits.php?id=319"></script></span> </h3> <div class="share">  <div id="bdshare" class="bdshare_t bds_tools get-codes-bdshare"> <a class="bds_tsina"></a> <a class="bds_qzone"></a> <a class="bds_tqq"></a> <a class="bds_hi"></a> <a class="bds_qq"></a> <a class="bds_tieba"></a> <span class="bds_more">更多</span> <a class="shareCount"></a> </div> <script type="text/javascript" id="bdshare_js" data="type=tools&uid=6513684" ></script> <script type="text/javascript" id="bdshell_js"></script> <script type="text/javascript"> document.getElementById("bdshell_js").src = "http://bdimg.share.baidu.com/static/js/shell_v2.js?cdnversion=" + Math.ceil(new Date()/3600000) </script>  </div> </div> <div class="content"><p style="text-align: center; line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;"><a href='http://www.buildinstantrapport.com/product/lsyt/' target='_blank' class='key_tag'><font color=#136ec2><strong>硫酸亞鐵</strong></font></a>處理廢水的混凝過程及與其它絮凝劑的投加順序</span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;"><span style="font-family: 宋體; font-size: 14px;">　　因為硫酸亞鐵的主要成份是二價鐵離子（</span><span style="font-family: Calibri; font-size: 14px;">Fe2</span><span style="font-family: 宋體; font-size: 14px;">＋），在混凝過程中部份二價鐵離子氧化成三價鐵離子</span><span style="font-family: Calibri; font-size: 14px;">(</span><span style="font-family: 宋體; font-size: 14px;"><a href='http://www.buildinstantrapport.com/product/jhlst/' target='_blank' class='key_tag'><font color=#136ec2><strong>聚合硫酸鐵</strong></font></a>）進行吸附有機物，如果投加量控制得不是很好的話，其多余的鐵離子會沉淀在廢水中，導致水體的色度增加，呈現出黃色的狀態</span><span style="font-family: Calibri; font-size: 14px;">,</span><span style="font-family: 宋體; font-size: 14px;">也就是我們常說的硫酸亞鐵二次污染返色現象。</span></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;"><span style="font-family: 宋體; font-size: 14px;"><img src="/data/upload/image/20151208/1449578838403091.jpg" title="硫酸亞鐵處理印染廢水.jpg" alt="硫酸亞鐵處理印染廢水.jpg" style="float: right; width: 298px; height: 221px;" width="298" height="221" border="1" vspace="1"/></span></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;"><span style="font-family: 宋體; font-size: 14px;">　　在印染廢水采用硫酸亞鐵混凝處理的過程中，如果亞鐵投加過量，則會使得其殘余的鐵離子進入厭氧池中與廢水中的硫化染料發生反應</span><span style="font-family: Calibri; font-size: 14px;">,</span><span style="font-family: 宋體; font-size: 14px;">反應生成大量的硫化亞鐵，硫化亞鐵是一種細小的顆粒狀黑色有機物。使得在氧化曝氣中，由于曝氣生化的作用，生成鐵氧化物后使水體呈現黑色。</span></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei';"><span style="font-family: 宋體; font-size: 14px;"><span style="font-family: 宋體;">　　采用芬頓法處理硫酸亞鐵時，硫酸亞鐵投加量控制不當則使得對廢水</span><span style="font-family: Calibri;">COD</span><span style="font-family: 宋體;">的去除率下降，增加出水的</span><span style="font-family: Calibri;">COD</span><span style="font-family: 宋體;">。并影響到廢水的生化處理系統。且硫酸亞鐵與聚合硫酸鐵屬強酸性化合物，投加會使水的</span><span style="font-family: Calibri;">pH</span><span style="font-family: 宋體;">值下降，電導率變化不大，水解后釋放出</span><span style="font-family: Calibri;">H</span></span><span style="font-family: 宋體; font-size: 16px; vertical-align: super;">＋</span><span style="font-family: 宋體; font-size: 14px;">，對硫化物的去除率下降（硫酸亞鐵去除硫化物過程）；</span></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei';"><span style="font-family: 宋體; font-size: 14px; line-height: 48px;">　　</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">所以在使用硫酸亞鐵混凝處理廢水時，或采用芬頓試劑處理廢水時都需要嚴格通過實驗配比好其投加量，以防止投加不當導致其混凝效果變差。</span></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;">　　工業廢水化學處理過程中，通常采用多種藥劑進行配合投加混凝沉淀，使得其對各種污染物得以去除。比如印染廢水的處理我們通常采用硫酸亞鐵<span style="font-family: Calibri; font-size: 14px;">+</span><span style="font-family: 宋體; font-size: 14px;">石灰的方法進行處理，硫酸亞鐵脫色、除鉻，除銅等金屬離子，石灰中和</span><span style="font-family: Calibri; font-size: 14px;">PH</span><span style="font-family: 宋體; font-size: 14px;">值以及起到助凝的作用。電鍍廢水則通常采用硫酸亞鐵</span><span style="font-family: Calibri; font-size: 14px;">+</span><span style="font-family: 宋體; font-size: 14px;">復合堿進行預處理。</span></span></p><h1 label="標題居左" style="font-size: 32px; font-weight: bold; border-bottom-color: rgb(204, 204, 204); border-bottom-width: 2px; border-bottom-style: solid; padding: 0px 4px 0px 0px; text-align: left; margin: 0px 0px 10px; line-height: 3em;"><span style="line-height: 3em; font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;">硫酸亞鐵與石灰的投加順序</span></h1><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei';"><span style="font-family: 宋體; font-size: 14px; line-height: 48px;">　　</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">硫酸亞鐵有很強的還原性，在廢水中迅速水解生成氫氧化亞鐵膠體與硫酸，因為硫酸亞鐵屬酸性所以他的投加會降低廢水的堿度，石灰在這個過程中主要起到一個調</span><span style="font-family: Calibri; line-height: 3em; font-size: 14px;">PH</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">值與助凝的作用，石灰與硫酸亞鐵在廢水中都會與污染物反應生磁氫氧化鐵膠體沉淀，并對廢水中的懸浮小顆粒、帶色基團、非可溶性有機物進行吸附沉淀處理。</span><br/></span></p><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei';"><span style="font-family: 宋體; font-size: 14px; line-height: 48px;">　　</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;"> 1、先投加硫酸亞鐵可以使得亞鐵離子在酸性條件下呈現的氧化性，對廢水中銅、鉻達到去除作用。</span><span style="font-family: Calibri; line-height: 3em; font-size: 14px;">2</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">、先投加石灰，屬于先對廢水調</span><span style="font-family: Calibri; line-height: 3em; font-size: 14px;">PH</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">值，將廢水</span><span style="font-family: Calibri; line-height: 3em; font-size: 14px;">PH</span><span style="font-family: 宋體; line-height: 3em; font-size: 14px;">值調節成堿性，鐵在堿性條件下呈還原性，能更好地促進廢水中的帶色基團進行還原脫色處理、還原六價鉻等及進行芬頓反應。</span></span></p><h1 label="標題居左" style="font-size: 32px; font-weight: bold; border-bottom-color: rgb(204, 204, 204); border-bottom-width: 2px; border-bottom-style: solid; padding: 0px 4px 0px 0px; text-align: left; margin: 0px 0px 10px; line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px; line-height: 3em;">硫酸亞鐵與<a href='http://www.buildinstantrapport.com/product/jbxa/' target='_blank' class='key_tag'><font color=#136ec2><strong>聚丙烯酰胺</strong></font></a>的投加順序</span></h1><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;">　　<span style="font-family: 宋體; font-size: 14px;">硫酸亞鐵與聚丙烯酰胺在廢水中都具有絮凝效果，但聚丙的絮凝沉淀效果要強于硫酸亞鐵。通常是先投加硫酸亞鐵再加入聚丙，這樣使得硫酸亞鐵水解后與有機污染物形成的礬花顆粒，在聚丙加入后的強入絮凝下將形成的這些細碎的絮體快速粘結成巨形團狀，并在重力的作用下沉淀形成密實的污泥。如果先投加聚丙烯酰胺則會使硫酸亞鐵投加后并不會產生多大的絮凝作用，從而導致藥劑的失效。</span></span></p><h1 label="標題居左" style="font-size: 32px; font-weight: bold; border-bottom-color: rgb(204, 204, 204); border-bottom-width: 2px; border-bottom-style: solid; padding: 0px 4px 0px 0px; text-align: left; margin: 0px 0px 10px; line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;">硫酸亞鐵的混凝過程</span></h1><p style="line-height: 3em;"><span style="font-family: 微軟雅黑, 'Microsoft YaHei'; font-size: 14px;">　　<span style="font-family: 宋體; font-size: 14px;">硫酸亞鐵與聚合硫酸鐵有著優良的混凝與脫色性能，在各種廢水中通過對廢水中污染有機物或懸浮物壓縮電層、吸附電中和、聚合凝聚、網捕沉淀（吸附、架橋、交聯）等一系死的反應使得污染物形成礬花沉淀。并破壞廢水中的發色基團使得其脫色效果非常的好。許多企業也利用硫酸亞鐵進行除磷與去</span><span style="font-family: Calibri; font-size: 14px;">COD</span><span style="font-family: 宋體; font-size: 14px;">等的處理。那么硫酸亞鐵在中會不會對廢水造成壞的影響？</span></span></p></div> <h3 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